On freezing mixtures made with solid carbonic acid
نویسندگان
چکیده
منابع مشابه
Tunnelling in carbonic acid.
The cis,trans-conformer of carbonic acid (H2CO3), generated by near-infrared radiation, undergoes an unreported quantum mechanical tunnelling rotamerization with half-lives in cryogenic matrices of 4-20 h, depending on temperature and host material. First-principles quantum chemistry at high levels of theory gives a tunnelling half-life of about 1 h, quite near those measured for the fastest ro...
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Carbonic acid (H2CO3) is a molecule right at the interface between organic and inorganic chemistry. In fact, according to some definitions it is an organic molecule, while according to others it is an inorganic molecule. Its exceptionality can also be recognized from the fact that it formally belongs neither to the mononor dicarboxylic acids, even though it is a C1 diprotic acid. The diprotic n...
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ژورنال
عنوان ژورنال: The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science
سال: 1888
ISSN: 1941-5982,1941-5990
DOI: 10.1080/14786448808628283